Enantiomeric excess

Enantiomeric excess

Der Enantiomerenüberschuss, oder kurz e.e.-Wert (von englisch: enantiomeric excess), gibt den Überschuss eines Enantiomers in einem Gemisch an. Er ist definiert als

e.e. =  \frac{m_1 - m_2}{m_1 + m_2}\cdot 100%

mit m1: Masse des Enantiomers im Überschuss, m2: Masse des Enantiomers im Unterschuss

Bei einem Racemat ist demnach e.e.= 0 %, bei einer enantiomerenreinen Verbindung ist e.e.= 100 %

Siehe auch: Enantioselektive Synthese, Enantioselektive Katalyse


Wikimedia Foundation.

Игры ⚽ Поможем написать реферат

Schlagen Sie auch in anderen Wörterbüchern nach:

  • Enantiomeric excess — The enantiomeric excess of a substance is a measure of how pure it is. In this case, the impurity is the undesired enantiomer (the opposite handed mirror image of a chiral compound). Definition Enantiomeric excess is defined as the absolute… …   Wikipedia

  • enantiomeric excess — enantiomero perteklius statusas T sritis chemija apibrėžtis Enantiomerų kiekių medžiagoje skirtumas (%). atitikmenys: angl. enantiomeric excess; optical yield rus. оптический выход; энантиомерный избыток ryšiai: sinonimas – optinė išeiga …   Chemijos terminų aiškinamasis žodynas

  • Homochirality — is a term used to refer to a group of molecules that possess the same sense of chirality. Molecules involved are not necessarily the same compound, but similar groups are arranged in the same way around a central atom. In biology homochirality is …   Wikipedia

  • Murchison meteorite — Murchison A Murchison meteorite specimen at the National Museum of Natural History (Washington) Type Chondrite Class Carbonaceous chondrite …   Wikipedia

  • Optische Reinheit — Die optische Reinheit ist ein Begriff aus der Chemie, genauer aus der Stereochemie, zur Beschreibung der Zusammensetzung eines Gemisches von Enantiomeren (zueinander spiegelbildliche chirale Moleküle). Die optische Reinheit (englisch optical… …   Deutsch Wikipedia

  • Kinetic resolution — In kinetic resolution, two enantiomers show different reaction rates in a chemical reaction, thereby creating an excess of the less reactive enantiomer.[1] This excess goes through a maximum and disappears on full completion of the reaction.… …   Wikipedia

  • Enantioselective synthesis — Enantioselective synthesis: Sharpless epoxidation Enantioselective synthesis, also called chiral synthesis, asymmetric synthesis or stereoselective synthesis, is organic synthesis that introduces one or more new and desired elements of… …   Wikipedia

  • Chiral pool synthesis — is a strategy that aims to improve the efficiency of chiral synthesis. It starts the organic synthesis of a complex enantiopure chemical compound from a stock of readily available enantiopure substances. Common chiral starting materials include… …   Wikipedia

  • Nazarov cyclization reaction — The Nazarov cyclization reaction (often referred to as simply the Nazarov cyclization) is a chemical reaction used in organic chemistry for the synthesis of cyclopentenones. The reaction is typically divided into classical and modern variants,… …   Wikipedia

  • Chiral derivatizing agent — A chiral derivatizing agent (CDA) also known as a chiral resolving reagent, is a chiral auxiliary which can convert a mixture of enantiomers into diastereomers in order to analyse the quantities of each enantiomer present within the mix. In NMR… …   Wikipedia

Share the article and excerpts

Direct link
Do a right-click on the link above
and select “Copy Link”